The rare earth elements (REE) are used in a wide range of applications, including clean energy technologies. Their unique properties make them indispensable in applications such as permanent magnets, catalysts, as polishing agents and other uses. Rare earth permanent magnets constitute the leading end-use market with a global demand share in 2020 of 29% (Figure 1).

Figure 1  REE demand in 2020 by end-use sector. Data from IRENA (2022).

Rare earth elements are subdivided into two groups based on their chemical properties (Tables 1 and 2). Scandium (Sc), is sometimes classed as a rare earth element, however it has different properties which set it apart from this group.

The key elements for the manufacture of permanent magnets are neodymium (Nd), dysprosium (Dy), praseodymium (Pr) and terbium (Tb), used in Nd(±Dy±Tb±Pr)-Fe-B magnets, and samarium (Sm) which is used in Sm-Co magnets.

It is important to note that deposits of individual REE don't occur in nature; however, some deposit types can be more LREE or HREE enriched.

Table 1  Light rare earth elements.
Element Element symbol
Lanthanum La
Cerium Ce
Praseodymium Pr
Neodymium Nd
Promethium Pm
Samarium Sm
Europium Eu
Gadolinium Gd
Table 2  Heavy rare earth elements.
Element Element symbol
Terbium Tb
Dysprosium Dy
Holmium Ho
Erbium Er
Thulium Tm
Ytterbium Yb
Lutetium Lu
Yttrium Y

Acquiring REE

Supply chain

The rare earth elements (REE) supply chain is complex, global and includes multiple actors that interconnect to deliver the materials, components and products-bearing REE that are essential for a range of applications. The rare earth elements supply chain comprises the stages of exploration, extraction, processing, manufacture, use and end-of life. Each one of the stages includes material transformation processes, in which REE are transformed into different forms (e.g. from ore to oxides and metals).

REE are fundamental for decarbonisation technologies, such as wind-powered energy generation (i.e. wind turbines) and electric vehicles, which rely on the availability of permanent magnets. REE availability is highly concentrated in China and the overall market has been volatile, with rising concerns around security of supply in the global and UK communities.

The future outlook for REE is that of increasing demand for all markets, but especially so for permanent magnets and metal alloys and the related REE (e.g. Nd, Dy, Pr, Tb). There are several challenges to bringing new supply on stream and extend beyond the physical imbalance between supply and demand. Environmental, economic, social and political challenges also exert significant influence on the future of the REE supply chain.

In Met4Tech, we attempt to understand and quantify the UK REE supply chain, including the reverse options focusing on wind turbines and electric vehicles as key applications. Our aim is to identify global influences and bottlenecks that may impact the UK, but more importantly the identification of circular economy opportunities.

Figure 2  REE supply chain.

Exploration

Exploration for REE experienced a boom, which started in 2010, after China placed export restrictions on their supply of REE to the rest of the world. This boom has developed over the past decade, further fuelled by increased prices and increased demand for certain REE.

Exploration for REE occurs on every continent on Earth with the exception of Antarctica. Some of the projects and target areas are at the very early stages of exploration, whilst others are more progressed having published resource and reserve estimates.

Figure 3  Global map of REE mines, deposits and occurrences, with approximate locations indicated. source: Deady (2021).

Deposits, occurrences and mines that contain REE are known across the globe. They occur in a range of deposit types in a variety of geological settings, the most important deposits are associated with carbonatites, ion adsorption clays and alkaline igneous rocks. Carbonatites are igneous rocks that contain more than 50% modal carbonate and are typically enriched in the LREE. Ion adsorption clays typically occur as tropical weathering crusts on top of igneous lithologies such as alkaline granites. During weathering the REE are released from primary igneous minerals and are then adsorbed or bonded to secondary clays, creating an easily processed REE-rich deposit. The REE content of ion adsorption clay deposits can be variable but currently most of the world's HREE are extracted from these deposit types. Alkaline igneous rocks can be important hosts for REE mineralisation, for example REE are extracted from a large igneous complex in northern Russia. Other deposits associated with igneous rocks, that contain the mineral eudialyte, could be a potential future source of REE if appropriate processing technologies are developed. REE are also sourced from mineral sands and placers across the globe. Monazite and xenotime are the main minerals produced from these particular deposit types.

Reserves of contained rare earth oxides (REO)

Figure 4  Global distribution of REE reserves. Data source: USGS (2023)

Publicly available data released by exploration and mining companies, and published historic data indicate that there are significant global resources and in some cases reserves of REE. These data have been converted to contained (REO) to make them comparable. However, due to the lack of available data for the majority of known deposits and operating mines in China it's difficult to make a true comparison, with China having some of the most significant resources and reserves in the world. Some deposits will have a higher grade of HREE or LREE, depending on the geology of the deposit, but this is, in the majority of cases, indistinguishable from the available public data.

Global distribution of rare earth element reserves expressed as tonnes of REO. Figure 4 shows global distribution of reserves, with RoW (rest of world) comprising countries with resources of less than 2 Mt, including Canada, South Africa, Tanzania and Greenland.

Extraction

REE are extracted from three principal sources:

  1. hard-rock deposits (i.e. carbonatites and alkaline igneous rocks)
  2. heavy mineral sands, and
  3. ion adsorption clays
Figure 5  REO production by country 1992 to 2020. Data source: BGS World Mineral Production.

Global production from hard-rock deposits is dominated by China. However, there are hard-rock mines outside of China including Mount Weld in Australia, Mountain Pass in the USA and Lovozero in Russia. Production of REE from ion adsorption deposits is also heavily concentrated in southern Chinese provinces, but recent changes in environmental legislation has prompted Chinese companies to source REE from similar deposits in Myanmar. Production from heavy mineral sands is dominated by India and Madagascar, but the volume of production is much lower than from other deposit types. Irrespective of deposit type global primary supply of REE is dominated by China and increasingly constrained as Chinese internal demand starts to outstrip domestic supply.

The diversity of REE-bearing deposits requires a variety of mining and processing techniques to be used for their exploitation. Because REE are typically exploited as by-products alongside the extraction of other metals, these will dictate the economics of the operation and the type of mining used. At most mines, beneficiation (i.e. processing of the raw ore to remove gangue minerals) generally occurs on site to produce a REE mineral concentrate that can be shipped for further processing. The exploitation of unconventional REE-ore minerals (e.g. eudialyte, allanite, etc.) will require new methods of beneficiation and processing, as there are currently no commercial-scale processes for REE-bearing minerals other than bastnäesite, monazite, xenotime and loparite. Over the past decade there has been a marked diversification in global REE supply, with China, which dominated mine production of REO, dropping it's market share from >95% in 2010 to 68% in 2020.

Processing

After mining, REE ores are processed to increase their REE content. Initial concentration is normally undertaken at, or close to, the mine site and involves crushing the ore and separating REE-bearing ore minerals from the gangue (uneconomic) minerals, using a range of physical (e.g. magnetic separation and froth floatation) processes that depend on the ore type being processed. Chemical processes (e.g. calcining and acid leaching) are used to further separate the REE from their ore minerals.

Separation of the individual REE from each other is challenging due to their similar chemical properties; however, selective oxidation or reduction and hydrometallurgy (i.e. typically ion exchange and solvent extraction) have been successfully employed to separate the individual REE.

Hydrometallurgical processing is commonly used to separate and purify REE according to the following three stages:

  1. Dissolution of the rare earth content in acid, sometimes at elevated pressure and temperature.
  2. Separation of the different REE into pure and concentrated solutions, by solvent extraction or ionic liquid extraction and ion exchange. The separation of the individual REE is the most difficult part of the whole REE value chain.
  3. Generation of individual and pure rare earth elements.
Figure 6  REE processing routes for bastnäesite, monazite and xenotime. Figure after Smith et al. (2017).

Processing of REE ores and concentrates to produce REE-metals and REE-chemicals (e.g. oxides, carbonates and nitrates, etc.) predominantly occurs in China, which accounts for more than 80% of REE processing. However, there is processing capacity in Japan, India, Malaysia and Russia, with REE-refining plants also planned in Norway, Sweden, the United Kingdom, Canada and the United States (tables 3 and 4).

Table 3  Operational REE processing facilities. Compiled by Richard Shaw (BGS).
Company Country Product
India Rare Earths India REE chlorides
Lynas Malaysia REE oxides
China Rare Earth Group China REE oxides, carbonates, salts and metal
China Northern Rare Earth Group China REE oxides, carbonates, salts and metal
Toyota Tsusho India REE oxides and carbonates
Solikamsk Russia REE oxides
Silmet Estonia REE metals and alloys
Solvay France REE oxides and organometallics
Energy Fuels (offtake for monazite with Neo Performance Materials) United States REE carbonates
Treibacher Austria REE oxides, salts and metal
Vietnam Rare Earth JSC Vietnam REE oxides and metal
MP Materials United States REE oxides
Table 4  Planned REE processing facilities. Compiled by Richard Shaw (BGS).
Company Country Product
LKAB Sweden REE oxides
Iluka Resources Australia REE oxides
REEtec (JV with Yara) Norway REE oxides and nitrates
Pensana United Kingdom REE oxides
Peak Resources (offtake agreement with Shenghe) United Kingdom REE oxides
Pulawy (JV with Makango) Poland REE oxides
SRC Canada REE oxides and metal
Vital Metals Ltd (offtake agreement with REEtec) Canada REE oxides
Blue Line (JV with Lynas) United States REE oxides, carbonates, nitrates and acetates
Texas Mineral Resources (development agreement with USA Rare Earth) United States REE oxides
Ucore United States REE oxides
Northern Minerals Australia REE carbonates

Drivers and alternatives

Secondary sources

To tackle climate change, there is a move towards global decarbonisation that will lead to increased demand for a range of REE in the coming decades. As resources of primary REE are finite and global supply is highly dependent on China, adopting circular strategies including reuse and recycling may improve the security of supply of REE for countires like the UK, but also alleviate pressure on primary supply.

Products with embedded REE

Many REE (e.g. Nd, Dy, Pr, Tb) are used in the production of NdFeB magnets. Figure 7 shows the end-use share of NdFeB magnets. These NdFeB magnets embedded in REE-bearing products have different lifespans, ranging from 2 to 3 years in consumer electronics, 9 to 13 years in EVs, and 25 to 35 years in wind turbines. REE plays an important role in green and clean energy technologies, including wind turbines, electric vehicles, fuel cells, and lighting. EVs sales and wind turbine installations have been increasing in the UK during the past few years. Therefore, EVs and wind turbines have a high potential to be future secondary sources of supply of certain REE (Nd, Dy, Pr, Tb). The availability of secondary sources of REE depends on several factors, including historical production, product lifespan, collection rates and the yields of recycling. When REE-bearing products enter the end-of-life stage, there are many opportunities to retain the highest value REE within the UK economy.

Figure 7  End-use share of NdFeB magnets. Data from IRENA (2022).

Current situation and challenges

Potential secondary sources of REE include industry by-products, wastewater and end-of-life products. Among them, the EoL products have the greatest potential for secondary supply. Since the mid-1980s, NdFeB magnets have been manufactured, and widely used, such as in hard disk drives and electric motors. Considering product lifespan, there are already opportunities to recycle the REE within NdFeB magnets as a secondary supply. However, only 1% of REEs are recovered, and less than 1% of NdFeB magnets are recycled. The main destinations of REE-bearing waste include exports to other countries, landfilling and losses as contaminants in various waste streams (Figure 2). REE are technically and economically difficult to be collected and recycled because of the small quantities of REE in many applications, the complexity of products, lack of support for developing novel segregation and scaling up the recycling processes. In the future, there are opportunities to recycle REE from EVs and wind turbines. Therefore, it is important to monitor REE flows across the lifecycle stages at different levels (i.e. substances, components, products), as well as develop end-of-life management to imporve circularity of REE supply.

In the near future, there will be rapidly growing REE demand. In the short term, secondary REE are unlikely to overtake primary supply. In the long term, developing recycling technologies and infrastructure could contribute to tackling the criticality of REE. The stock modelling can show the potential quantities available for recycling and highlight the need for future recycling capacity.

Recycling technologies and circular strategies

Currently, there is no effective REE waste collection and separation systems for REE-bearing products. Various recycling technologies to separate and recycle REE are being developed. Table 5 lists the existing recycling and recovery pilot plants and market players. Many of these technologies are still limited to the laboratory or pilot-scale and are not mature enough to be commercialised yet. REE-bearing waste could be recycled or recovered into oxide forms or alloy forms, as well as being reused, repaired, refurbished, or remanufactured as secondary components returning to the production process.

The page on circular flows further explains a range of recycling technologies and circular strategies for technology metals that are embedded in different components and end-use products. Different circular strategies will result in varying quality and quantity of secondary REE, cost and revenue, as well as social and environmental impacts, therefore, it is important to consider suitable circular strategies for different REE-bearing products in the UK. This relies on whole system thinking to determine the trade-offs between these circular strategies and how these strategies may operate in conjunction with each other, but also understanding the effects of secondary REE use in manufacturing new products.

Table 5  Ownership and location of REE recycling pilot-plants.
REE recycling pilot-plant Country
University of Birmingham United Kingdon
Hypromag United Kingdon
STENA Recycling Sweden
Magneti Ljubljana Slovenia
Solvary SA Belgium
Umicore Belgium
Osram Licht AG Germany
Geomea Resources Canada
Energy Fuels, Inc USA
REEcycle, Inc USA
Global Tungsten & Poweders Corp United States
Hitachi Metals, Ltd Japan

Policy intervention

REE are considered as critical mineral resources, therefore, several government interventions are needed to support both the primary and secondary supply of REE. In terms of secondary sources, financial investment is needed in research and development (research and development) focused on resource efficiency, separation and recycling technologies, as well as infrastructure for the collection and recycling of REE-bearing products.

Collaboration, both globally and domestically, is key to creating a diverse primary and secondary REE market and resilience of both primary and secondary supply. For example, the Rare Earth Industry Association (REIA) and the European Raw Materials Alliance (ERMA) gather togther REE stakeholders to exchange data, information and knowledge related to REE. Traceability is particularly significant for creating a circular economy system of REE. It is important for governments, academia and industry stakeholders across the REE value chain to collaborate in developing a circular economy system and improve the traceability and transparency of REE.

Education includes training the next-generation of skilled workers across the REE value chain, with a focus on the circular economy, while educational campaigns for consumers can improve understanding of the social and environmental impacts of the REE. Education has the potential to drive social behaviour change to circular use and recycling of REE-bearing products, especially for consumer electronics and electric mobility.

Regulatory intervention can be more powerful in supporting the secondary supply of REE. The extended producer responsibility (EPR) scheme can enhance not only the producers' responsibility for EoL product management, but also the product design for disassembly, reuse, repair and recycling. Further regulatory issues such as taxes, international trade laws, standardisation, investment and environmental regulations are discussed on the legal and regulatory webpage.

Focus on the UK

Background geological information and challenges

In the UK there are many documented occurrences of REE-bearing minerals, which include: monazite, allanite fergusonite, chevkinite, gadolinite and synchysite. However, in most cases these occurrences comprise only minor low tenor REE enrichment over restricted areas. For example, many of these minerals are found as rare accessory phases in some Tertiary granites, or are minor accessories to lead-zinc-fluorite mineralisation in the Northern Pennine Orefield (Walters and Lusty, 2011). To date there has been no mine production of REE-bearing minerals in the UK, nor are there any deposits in which REE reserves or resources have been reported. To date there has only been very limited evaluation of the REE potential in the UK. During the early 1990s BGS made a preliminary assessment of the REE contents of three late Caledonian alkaline intrusive complexes in north-west Scotland. Rock and drainage samples from Loch Borralan, Loch Ailsh and Loch Loyal were analysed for Ce, La and Y (Shaw and Gunn, 1993). During this period BGS undertook an assessment of the economic potential of mudstone-hosted nodular monazite in south-central Wales (Smith et al., 1994). More recently a BGS-hosted MSc student reappraised drill core from the ultramafic section of the Loch Borralan Complex to further assess its potential as a REE resource (Griffith, 2011). In 2013 BGS studied the formation of late-stage allanite-bearing veins associated with the Loch Loyal Syenite Complex (Hughes et al., 2013; Walters et al., 2013).

Figure 8  Location of the principal REE occurrences in the United Kingdom. From Shaw and Gunn (2020).

Even though REE minerals are known to occur in the UK, many of them are quite rare and are typically found in minor amounts in a few localities. It is worth noting that REE have never been commercially extracted in the UK, nor has there been any systematic exploration for REE.

A priority target for further investigation is the Cnoc nan Cuilean Intrusion in north-west Scotland. The hydrothermal, allanite-bearing veins that crosscut the intrusion contain the highest REE grades recorded in the UK (up to 2 wt. % TREO) (Walters et al., 2013). The known occurrence of significant hydrothermal, REE-mineralised veins associated with alkaline igneous rocks elsewhere in the world provides a strong basis for evaluating this area further. However, there is currently no commercial process for extracting REE from allanite; this coupled with the thin and discontinuous nature of the veins, makes them unlikely to be economic.

It is also important to note that previous work by BGS on the Caledonian alkaline intrusions of northwest Scotland has focussed on the PGM potential 6 of selected parts of these bodies. Systematic investigations over the entirety of these complex intrusions are recommended in order to fully evaluate their REE potential.

UK critical minerals strategy and market opportunities

A recent UK criticality assessment published by BGS, commissioned by BEIS, shows REE high on the list. The security of a rare-earth material supply is crucial to the UK's electrification ambitions which are required to meet the UK government's net zero target. The UK's Critical Minerals Strategy announced in 2022 aims to accelerate the growth of the UK's domestic capabilities; collaborate with international partners; and enhance international markets to make them more responsive, transparent and responsible. There are significant opportunities for the UK to deploy its expertise and forefront research assets for innovation in these areas and establish REE market share.

To build up the sustainable supply chain of REE in the UK, the UK would require diversifying the supply of REE, and exploring the possibility of mining and refining ores into metals and alloys. The UK has a leading role in research and development and education of metal refining and green chemistry. Therefore, it is important to use UK strength to develop new innovations for the chemical treatment and separation of REEs. Furthermore, there are many UK-based original equipment manufacturers (OEMs). Thus, it is also suggested to provide incentives for OEMs to develop magnet production and its end-of-life management.

Recycling of REE-containing magnets and products for secondary supply

The UK will need to secure significant quantities of REE to achieve the electrification transition. There are supply risks and limits for domestic primary production. Hence, in the long term, it is crucial to develop an ecosystem for secondary supply. The current in-use stocks could provide buffer capacity if circular economy systems are established. In the future, assuming that the net-zero targets materialise, the UK stock in products could create viable circular economy business opportunities. As most of the current plants are still at the pilot scale, it is necessary to assess the technology readiness levels (TRLs) of the existing REE recovering technologies in the UK. The UK has expertise and capability in material science and REE recycling. For example, the University of Birmingham has strong research expertise in recovering REE. Investing in research and development and establishing a secondary supply chain could expand the recycling capacity of REE and stimulate further innovation in magnets, especially research into next-generation magnet materials.

More information

Further reading

Patil, A.B.; Paetzel, V.; Struis, R.P.W.J.; Ludwig, C. 2022. Separation and Recycling Potential of Rare Earth Elements from Energy Systems: Feed and Economic Viability Review. Separations 2022, 9, 56. DOI: 10.3390/separations9030056

Alves Dias, P., Bobba, S., Carrara, S., & Plazzotta, B. 2020. The role of rare earth elements in wind energy and electric mobility. European Commission: Luxembourg.

Jyothi, R. K., Thenepalli, T., Ahn, J. W., Parhi, P. K., Chung, K. W., & Lee, J. Y. 2020. Review of rare earth elements recovery from secondary resources for clean energy technologies: Grand opportunities to create wealth from waste. Journal of Cleaner Production, 267, 122048.

Binnemans, K., McGuiness, P. & Jones, P.T. Rare-earth recycling needs market intervention. Nat Rev Mater 6, 459-461 (2021). DOI: 10.1038/s41578-021-00308-w

Walton, A., Anderson, P., Harper, G., Mann, V., Beddington, J., Abbott, A., ... & Ogrin, R. (2021). Securing technology-critical metals for Britain.

The UK's Critical Minerals Strategy.

UK supply chain opportunity in materials for permanent magnets (pdf).

Contact

For questions regarding the project please contact Dr Evi Petavratzi.